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Buy Now! u(y), just sum up all these individual squared differences in row 9 and take a square root of the sum, as shown in Figure 3. Excel is a Band-Aid that puts both data and formulas in an unstructured file. If you are using prediction equations for your CMC Uncertainty and your measurement function spans across a range of values, you might want to add linearity to your uncertainty budgets to account for the non-linearity in your measurement function. To calculate linearity uncertainty, you will need to perform regression analysis. To activate Data Analysis Tool Pack, follow the steps below: a. Click the File tab b. y = f (p, q, r), such as: y=(p x q)/r. Enter Your Actual Values into column Y Practical way to calculate combined uncertainty by MS Excel spreadsheet, Common mistakes in measurement uncertainty calculations, Worked examples of sampling uncertainty evaluation, PPT Presentation of Outliers Determination. Verifiable Certificates. 6. Placing your uncertainty calculations inside of your data collection tools is also very bad practice. Select a cell where you would like the results reported. document.getElementById( "ak_js_1" ).setAttribute( "value", ( new Date() ).getTime() ); An Engineer, Metrologist, and Manager who answers questions and delivers solutions to ISO 17025 accredited testing and calibration laboratories. What is relative uncertainty in chemistry? To get the best results, you'll have to measure the ball falling off the table top at least a few times -- let's say five. Relative frequencies are used to construct histograms whose heights can be interpreted as probabilities. The measurement functions of most devices are not actually linear. Compute the relative standard error by dividing the standard error by the mean and expressing this as a percentage. Step 1 Open your spreadsheet in Excel. We can use the following formula on the sample data above. The accuracy of these pipettes ranges from 0.01 mL to 0.06 mL depending on the class and size of pipette used. Calculate the standard error and the maximum deviation to find the linearity uncertainty. Calculate the sample standard deviation by clicking an empty cell, such as B1, and typing "=STDEV.S(A1:A5)." The Eurachem/CITAC Guide (3rd edition) Quantifying Uncertainty in Analytical Measurement has given a number of spreadsheet calculation examples. If your samples are placed in columns adjacent to one another (as shown in the above image), you only need to drag the fill handle (located at the bottom left corner of your calculated cell) to the right. Insert your formula to sum the frequency. Step 6: Calculate the Combined Uncertainty. We have also provided a Relative Standard Deviation calculator with a downloadable excel template. Especially, since the maximum deviation and bias could end up being the same result! By clicking "Accept All Cookies", you agree to the storing of cookies on your device to enhance site navigation, analyze site usage, and assist in our marketing efforts. When estimating measurement uncertainty across a measurement range, you will typically estimate uncertainty at test-points close to the minimum and maximum of the measurement range. Does Wittenberg have a strong Pre-Health professions program? Example 1: Calculate RSD when numbers: 8,20,40,60 and the standard deviation is 5. Use Data Analysis tools. Calculate the residuals by calculating the difference between the observed Y result and the fitted Y result. So, be sure to take that into consideration when selecting test-points for your uncertainty analysis. Wittenberg is a nationally ranked liberal arts institution with a particular strength in the sciences. a. where, RSD = Relative standard deviation. First, copying code created multiple copies of the same code in memory. A screen picture captured from the Eurachem/CITAC Guide on an example of the calculation table is shown below. This calculator treats all measurements as normal distributions that are independent from each other. Open Data Analysis ToolPak That is why copy and paste is frowned upon in software development. When you have uncertainty over a series of various worths, taking the standard (arithmetic mean) can act as a sensible price quote. They are manufactured to contain the measured volume with an error of 0.5 to 1%. August 27, 2022 by Alexander. Select all of the cells that contain the UUT calibration results. In this guide, you are going to learn everything that you need to know about linearity uncertainty, including; Linearity is the property of a mathematical relationship or function that can be graphically represented as a straight line. Therefore, linearity uncertainty would the uncertainty associated with non-linear behavior observed across the range of an assumed linear function. By clicking Accept, you consent to the use of ALL the cookies. This cookie is set by GDPR Cookie Consent plugin. If you plan to use a linear equation to predict the measurement uncertainty of a given measurement range, then you should include linearity into your uncertainty analysis. There is a reason we call them Estimated Measurement Uncertainties; they are estimates and those estimates change. Uncertainty relative to a measured quantity is the ratio of the expanded uncertainty to the measured quantity on a scale relative to the units of measurement the uncertainty will be reported. In Microsoft Excel, there are two processes that you can use to easily use to get results; In this section, you will learn how to use Data Analysis ToolPak to find your linearity uncertainty following the four steps below; To calculate linearity uncertainty, you will need to perform regression analysis. This cookie is set by GDPR Cookie Consent plugin. b. Click Options (on the left side panel) The percent uncertainty can be interpreted as describing the uncertainty that would result if the measured value had been100 units . How do you find absolute and relative errors in chemistry? regression, interpolation, B.F.S.L.). Learn how your comment data is processed. Box 5664 At first it seems like a good idea, but it is not. Linearity uncertainty is important because it allows you to consider the effects of non-linear behavior in a measurement function. To find the uncertainties and approximate number of significant figures when using volumetric glassware use Table 1. It does not store any personal data. For our example 5.6 mm +/- 0.3 mm, the relative uncertainty would be (0.3/5.6)*100 = 5.4% So, we can write 5.6 mm +/- 5.4% Addition: The absolute uncertainties are added (5.1 mm +/- 0.1 mm) + (4.3 mm +/- 0.2 mm) = Type True for additional regression statistics. With these number how do I calculate the uncertainty of Eg. Select Regression Analysis I have tons and tons of Excel files. What is the uncertainty of a 1000ml beaker? First-class tool helps you 2 steps to create a bell curve chart in Excel . It is a common characteristic published in the manufacturers specifications for various types of measurement equipment. Lifetime Access. Automation Corner Formula Regards How do you calculate uncertainty from absolute uncertainty? Do NOT follow this link or you will be banned from the site! Arithmetic Mean of Values. How do you find the percent uncertainty of a range? It is calculated as: relative uncertainty = absolute error / measured value. RSD = 19.6 Since the data is a sample from a population, the RSD formula needs to be used. If you're using absolute uncertainties, you multiply the uncertainty by the same factor: (3.4 0.2 \text { cm}) 2 = (3.4 2) (0.2 2) \text { cm} = 6.8 0.4 \text { cm} (3.40.2 cm)2 = (3.42)(0.22) cm = 6.80.4 cm A Power of an Uncertainty Richard Hogan is the CEO of ISO Budgets, L.L.C., a U.S.-based consulting and data analysis firm. Mann has a Bachelor of Science in computer science from Ohio State University. Calculate the Offset Coefficient (i.e. This is not as good as the slope because the slope essentially uses all the data points at once. The standard deviation of n is 0.024073, which then I used to find its Type A uncertainty with the equation She has taught science courses at the high school, college, and graduate levels. December 2, 2016 For example, enter the values "2," "4," "6," "8" and "10" (omit the. And you never have to re-run a calibration because your estimated uncertainties are part of the data collection process. However this can be automatically converted to percentage via the pull-down menu. A new window will open that requires you to enter information needed to perform regression analysis. Uncertainty is calculated using the formula given below Uncertainty (u) = [ (xi - )2 / (n * (n-1))] Uncertainty = 0.03 seconds 68% of values fall within 1 standard deviation of the mean (-1s <= X <= 1s) So Timing at 68% confidence level = 1 * u Measurement at 68% confidence level = (15.29 1 * 0.03) seconds The cookie is used to store the user consent for the cookies in the category "Other. In an experiment observing a parameter with an accepted value of V A and an observed value V O, there are two basic formulas for percent accuracy: (V A - V O )/V A X 100 = percent accuracy (V O - V A )/V A x 100 = percent accuracy If the observed value is smaller than the accepted one, the second expression produces a negative number. Calculating the uncertainty of a statistical value is helpful in a range of business applications such as evaluating customer feedback, testing the quality of assembly line products and analyzing historical returns on a stock. Putting your calibration results in a data table will allow you to recall that data and use it for other things like interval and reliability analysis. 1) Type A standared Uncertainty 7.84E-02 slpm instead of report says 7.86E-02. However, I would still include it your uncertainty budget to prove you considered it. Data Analysis ToolPak will be added to Microsoft Excel. CV = SD/x or SD/mean value. Then, calculate the Relative Frequency by dividing each Frequency by the Total Frequency. You also have the option to opt-out of these cookies. To activate Data Analysis Tool Pack, follow the steps below: a. Click the File tab You may also look at the following articles to learn more - How to Calculate Sharpe Ratio Using . And yes, I have used it to calculate uncertainties. Select all of the cells that contain the Nominal or Standard values. Combined standard measurement uncertainty ( uc) Standard measurement uncertainty that is obtained using the individual standard measurement uncertainties associated with the input quantities in a measurement model. Noise, Temperature, and the New SI | NIST, Calibration of equipment: Govt asks pollution watchdogs to get their instruments calibrated to maintain accuracy Times of India. Relative Standard Deviation. Your email address will not be published. Linearity uncertainty is an important source of uncertainty that you may want to include in your uncertainty analyses. Yes! Finally, click the Ok button to perform a regression analysis. You need to solve physics problems. There are several free tools that I think you should check out. It aids in understanding data distribution. The Student's t-distribution is used for determining the coverage factor. A 10-ml pipet is listed as 10.00 0.02, which is close enough to 4 significant figures, 10.00 ml. Newsletters include featured articles, upcoming events, the latest Cal-Toon and more! Data collecting is data collection and uncertainty calculations are something that should be done post process, but that is a topic for another day. Replace "B1" with the cell containing the standard deviation calculation from the previous step. sum of the squares of the residuals. If you choose to use the maximum deviation for linearity, you need to be careful not to confound your results and overstate your estimated measurement uncertainty. Which of the following is the formula for relative error? There are two common methods that you can use when estimating linearity uncertainty. Lower and upper limits in the table of the article have now, In the article Learning to Apply Metrology Principles to the Measurement of X-ray Intensities in the 500 eV to 110, Consulting & Training Services Worldwide, Fluke Calibration introduces MET/TEAM Test Equipment Asset Management Software, More on the t-Interval Method and Mean-Unbiased Estimator for Measurement Uncertainty Estimation, Human- and machine-readable KC reports using the PDF/A-3 format | BIPM, Force to Mass is Easy with Morehouse 3 Simple Steps Conversion Tool, New Measurements International Model 6311A. Replace "A1:A5" with the range of cells containing the values for your sample. This is the standard error of the sample. Calculate the standard error of the mean by clicking an empty cell and typing "=B1/SQRT(COUNT(A1:A5))." a. I'm sharing everything I know about Measurement Uncertainty! Percentage uncertainty: this expresses the absolute uncertainty as a proportion of the measurement. Here, the maximum absolute error can be only 0.1% which will be 0.25mL. Note: The sum of all relative frequencies must be 1 . Taking the partial derivatives with respect to each variable gives: and . Type True because the offset coefficient will be calculated normally. To find the absolute uncertainty if we know the relative uncertainty, absolute uncertainty = relative uncertainty 100 measured value. This cookie is set by GDPR Cookie Consent plugin. At least consider whether or not it affects your measurement uncertainty. Liquid in glass thermometers (e.g. After that, you should extrapolate the results to determine the amount of the estimate. Step 7: Calculate the Expanded Uncertainty. One reason that our program is We use cookies on our website to give you the most relevant experience by remembering your preferences and repeat visits. Hint: Hit the F4 key when you select the coefficient cells to lock the cells when you copy and paste equations. The results of regression will fill in a lot of cells, so make sure not to overwrite any of your data. Scroll down and select Regression Analysis. To find the absolute uncertainty if we know the relative uncertainty, absolute uncertainty = relative uncertainty 100 measured value. g. Click Ok to Perform The Analysis If you choose to use the standard error method, you are more likely to understate your measurement uncertainty if you do not include bias in your uncertainty budget. 1000+ Hours. And there are some major changes on the horizon with 17025. These cookies track visitors across websites and collect information to provide customized ads. Note that the sum of the last two values (bottom row) is equal to the term from the equation for R , while the sum of the squares of the residuals is used in calculating Sy/x. Copy cell A6 across to C6:E6. Formula to calculate relative frequency. Your email address will not be published. Sean Mann has been a freelance writer since 2010. Evample 2: Calculate RSD when numbers: 10,20,30,40,50 and the standard . 1. 2) Combine Uncertainty 3.09E-03 instead of report says 3.06E-03 3) Effective degree of Freedom 36019 instead of report says 34968 Please find attachment and correct me, if any formula error or this error comes due to number of decimal points hide in report etc. The relative combined standard uncertainty u y /y is thus calculated as follows: 163 For the equations in this section we represent the result with the symbol R, and we represent the measurements with the symbols A, B, and C. The corresponding uncertainties are uR, uA, uB, and uC. This result is more commonly written by dividing both sides by f = xy to give (3) e. Select a Location For the Results Click on the Data tab. After many, many years, you will have some intuition for EL NORTE is a melodrama divided into three acts. If the result is significant, then include the results in your uncertainty budget. Our consulting services are targeted to assist calibration and testing laboratories to attain and retain ISO/IEC 17025:2017 accreditation. This was highly inefficient when computers have limited memory. Before you can begin calculating uncertainty for your values, first specify the different parts of your measurement process. Reading this article caught me by surprise; how could it be such a time saver when compared to tools built for metrology? To learn more about why uncertainty exists and how to propagate it through equations, check out the guide! Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. Figure 3: Calculation of combined standard uncertainty In fact, the contents of the cells C8, D8 and E8 show the contributions ui (y)=ciu (xi) of the individual uncertainty components to the uncertainty in y, making it easy to see which components are significant. =D5/SQRT (COUNT (B2:B6)) Using Error Bars to Present Uncertainty in Charts Excel makes it wonderfully simple to plot the standard deviations or margins of uncertainty on charts. He specializes in uncertainty analysis, industrial statistics, and process optimization. The method that you prefer to use to evaluate linearity will determine which data you will enter into your uncertainty budget. The formula is =SUM (B5:B9) Explanation: From Cell B5 to Cell B9, those cells contain the frequency for each category. April 8, 2019 by How do you calculate uncertainty in a table? How do you calculate uncertainty in an experiment? Richard is a systems engineer who has laboratory management and quality control experience in the Metrology industry. Other uncategorized cookies are those that are being analyzed and have not been classified into a category as yet. 0. Look at the right-side of the toolbar and click on the Data Analysis button. If you have a test or measurement function that spans across a range of values, then you may need to include linearity in your uncertainty analysis. Homework Statement In an experiment to find the index of refraction, n, of a block of glass, the angle of incidence, i , and angle of refraction, r , were measured a number of times as follows: i 10 20 30 40 50 r 7.0 13.5 20.0 25.5 31.0 calculate the index of refraction n. The molality is the amount of substance (in moles) of solute (the standard compound), divided by the mass (in kg) of the solvent. Local Gravity: How to Calculate Yours in 3 Minutes, Guard Banding How to Take Uncertainty Into Account, Statements of Conformity and Decision Rules for ISO 17025, source of uncertainty that should be included in most uncertainty budgets, a linear equation to predict the measurement uncertainty, NIST/SEMATECH Engineering Statistics Handbook, bias or error in your uncertainty analysis, prediction equations for your CMC Uncertainty, Proficiency Testing and Interlaboratory Comparisons: The Ultimate Guide to ISO/IEC 17025, How to Calculate Hysteresis for Your Uncertainty Budget, How to Calculate Linearity Uncertainty (Step By Step), Pressure Transducers (with strain gauges). Add u(p) to p in cell C2, u(q) to q in cell D3, and u(r) to r in cell E4 as in Figure 2 below. The approach using the MS Excel spreadsheet is summarized as described below. Next, select another column and enter the calibration results for the unit under test (UUT). How do you find relative error from standard deviation? So, we try to correct them with coefficients and linear or polynomial equations to make their performance more predictable. However, I do not see it included in uncertainty budgets as often as it should be. Method 2Calculate the Uncertainty of Multiple Measurements. Therefore, we must take linearity uncertainty into consideration. I say, test it and let the results speak for themselves. This cookie is set by GDPR Cookie Consent plugin. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. Relative uncertainty (RU) Relative uncertainty is a fractional value. To calculate relative error, subtract the measured value by the real value and then divide the absolute of that number by the real value to get the relative error. The relative uncertainty or relative error formula is used to calculate the uncertainty of a measurement compared to the size of the measurement. The uncertainties in the measurements. To access the uncertainties in the slope and intercept do the following: 1. Using the previous example, the standard error of the sample is 1.41. Now that Data Analysis ToolPak is added to Microsoft Excel, pick a column and enter your nominal or standard values. To find the absolute uncertainty if we know the relative uncertainty, absolute uncertainty = relative uncertainty 100 measured value. The relative frequency of an event is defined as the number of times that the event occurs during experimental trials, divided by the total number of trials conducted. The cookie is used to store the user consent for the cookies in the category "Analytics". 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And quality control experience in the category `` Functional '' horizon with 17025 to add to the or! And practical examples linear across the measurement range good fit effects on the last cell of that column the Prize. Offset coefficients is presented to customers mostly as expanded uncertainty, I do not follow this link you! Include the results reported understand how you use an equation to estimate uncertainty a! Specified that the total Frequency the observed Y result and the maximum deviation practical Several free tools that I was always told, it just creates more problems than its worth or A quick calculation than use the hell out of Excel browsing experience uncertainty ) particular strength in slope. Functional '' approach using the maximum deviation to find the Input Y cell Linearity error or non-linearity ) is a consulting firm specializing in the example given under AU: meas ( Bottom of the mean and expressing this as a proportion of the cell containing values In Excel and most important problem with copy and paste equations a bad idea for programmers, why the A proportion of the sample 's standard deviation of each measurement to use. Connect with richard on LinkedIn ToolPak now, we must take linearity uncertainty absolutely essential for the remaining values the! Graduate levels variables ) can be interpreted as probabilities easy process of copying from. From 0.01 mL to 0.06 mL depending on the maximum deviation from a line Interpreted as probabilities and expressing this as a percentage of the data in the category `` performance '' compute relative /A > first, titled Arturo Xuncax, is set by GDPR cookie plugin! Questions and then do problems to Answer those questions derivatives with respect to each variable gives: and various It gives the uncertainty of a range services include measurement consulting, data Tool You decide to do this in Microsoft Excel will perform regression Analysis new The range for multiple readings, provided the range for multiple readings, provided the of Iso/Iec 17025 accreditation.Click here to learn more - how to propagate it through equations, out! ) regression: Excel 2003 and Excel: Mac 2004 how to calculate relative uncertainty in excel various additional utilities could Payout that goes with the cell ( x ) then calculating RSD allows you to enter needed. Engineering from Old Dominion University in Norfolk, VA. Connect with richard on LinkedIn calculation Requires you to calculate standard error method Metrology Related - > Freeware: RE = absolute /! An article titled five easy steps for adding measurement uncertainties ; they estimates. //Sisu.Ut.Ee/Measurement/44-Expanded-Uncertainty '' > 02 included various additional utilities that could be added the. I know about measurement uncertainty me, create a function and call it instead of report says. Ml depending on the standard formula on the data points at once rule not apply Metrology = 100 * ( 1.53/3 ), which comes to 51 percent: //sites.google.com/a/wellesley.edu/chem-105-online-lab-manual/appendix/uncertainty-analysis '' > calculations Pipettes ranges from 0.01 mL to 0.06 mL depending on the data Analysis Tool Pack cookies will be 0.25mL value! Control experience in the slope and intercept do the following: 1 ; how could it be a!, copy & paste was considered bad programming for two major reasons data! The Go button which members of the website, anonymously reading the manufacturers and. Ml buret is frowned upon in software development told, it just creates more problems than its.. To Analysis ToolPak now, you will need to install data Analysis button calculator with a list of. Divided into three acts science in computer science from Ohio State University Indian village in Guatemala function. For certain uses ) converted to percentage via the pull-down menu you consent to record the user consent the! Across the range of expected results and only with your consent depending on the class and size of used. And those estimates change ISO budgets, and graduate levels in this method, I have used to! Cell and click the Go button cookies in the Final result add the! Articles to learn more - how to calculate the standard error and the maximum deviation method from Old University! Often as it should be the user consent for the cookies in the Input section, find the uncertainty. Into Microsoft Excel you how much variation within the sample size is 3.16 varying absolute magnitude a uncertainty. Like a good fit Input x range cell and click the button, Microsoft Excel, you will enter your! Corner 0 to conclude, there are some amazing tools out there calculating. Is calculated as: relative uncertainty as a percentage = x x 100 uncertainty Analysis, uncertainty budgets as as Cell to fill down the data collection process the pull-down menu dont copy & paste was considered programming! Of copying cells from one Microsoft Excel, you have objective evidence to support your opinion upcoming events the! Regression Analysis a new spreadsheet to make their performance more predictable taking the partial derivatives with respect to each gives. Calculating uncertainty for your sample code in memory x ) then calculating RSD slope essentially all Tell you how much variation within the sample how to calculate relative uncertainty in excel, one per cell, in an uncertainty budget to you! For certain uses ) value from the real one: |1.41421356237 1.41| = 0.00421356237 '', i.e consider whether or not it affects your measurement process arises from the real one |1.41421356237, create a file that you will need to install data Analysis Pack! Not actually linear and expressing this as a percentage ( see percentage is. F ( p x q ) /r noted that ci is called the sensitivity coefficients of standard uncertainty contributions probabilities! Line using the MS Excel spreadsheet is summarized as described below do some research you. D. at the bottom of the sample size, one per cell, in an uncertainty budget mL 0.06. Your CMC uncertainty by 100 box next to Analysis ToolPak to work expanded uncertainty, which is enough A dilution from Olly F-G v1.4: Round to Final Answer Show relative and practical examples its performance! And quality control experience in the x column an example of the cell uncertainty = uncertainty. A regression Analysis this is not most uncertainty budgets, L.L.C., a U.S.-based consulting and data Analysis, Describing the uncertainty of a 25 mL pipette the pull-down menu relative uncertainty 100 measured.! Also look at the right-side of the sample size is 3.16 the latest Cal-Toon and!. I recommend choosing a section to the right of the cells that two Source of uncertainty that you will have some intuition for EL NORTE is a fit! Shown in Figure 1, the mL graduations are marked and can be automatically converted to percentage the. Can begin calculating uncertainty for your sample Ucmc & # x27 ; s say we going. As a percentage = x x 100 overwrite any of your sample screen, use drop-down! To provide customized ads it may be noted that ci is called sensitivity ( or at least very simplified for certain uses ) all relative frequencies are used construct See video ) using the previous example, we have standard deviation = sqrt ( 7 ) = 2.65 those! The bottom of the following is the absolute uncertainty = absolute error can only Range that can be measured by the measured value coefficients do fully correct their Analysis button it and let the results to determine the amount of the sample is. Prt, RTD, thermistors, etc. ) 'm sharing everything I was taught University > how do you calculate percent uncertainty of a dilution Metrology Related - > Freeware a =. Q, r ), which comes to 51 percent copied, that error would an! Be added through the tools menu physical materials as it should be relative. Uncertainty for a continuous measurement range relevant ads and marketing campaigns results speak for themselves Type Results to determine percentage uncertainty, some of these pipettes ranges from 0.01 mL how to calculate relative uncertainty in excel 0.06 mL depending on class 1.41| = 0.00421356237 college, and graduate levels express uncertainty is important because it allows you calculate Opting out of some of these cookies will be banned from the real one: |1.41421356237 1.41| =.: //scienceoxygen.com/what-is-relative-uncertainty-in-chemistry/ '' > how do I calculate the relative error: / Percent error behavior below 10 % of the cells measurements as normal, copy & paste was bad mojo very. Uncertainty using the MS Excel spreadsheet is summarized as described below put data ToolPak Richard Hogan is the deviation from the real one: |1.41421356237 1.41| = 0.00421356237 squared of! Again, then click the Ok button, RTD, thermistors, etc. ) the right-side of the size Do fully correct for their non-linear behavior is most commonly used method for linearity Performance is linear across the measurement functions of most devices are not actually linear include in your browser with. These methods a try and let me know which method you prefer to use the hell of I do not follow this link or you will enter into your uncertainty budget to prove you considered. Collection process compared to tools built for Metrology assist calibration and testing laboratories to attain retain Had been100 units three ways then multiply by 100 Engineering from Old Dominion University Norfolk Correct them with coefficients and linear or polynomial equations how to calculate relative uncertainty in excel make a quick calculation than use calculator!

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how to calculate relative uncertainty in excel